I've got a similar setup and I'm seeing the same issue. 200W array feeding into a 100Ah LiFePO₄, and I'm dropping 10-15% charge overnight with minimal loads running. Getting rather frustrating.
Before we assume it's parasitic drain, have a few questions that might help us both troubleshoot:
What's your actual load profile? I initially thought my problem was the battery, but realised my fridge was pulling far more than anticipated—even in eco mode. Are you monitoring individual circuits?
Is your BMS cutting the battery off at night? I had my Victron configured to protect the battery below 20%, which meant phantom loads were discharging it further. Worth checking your settings.
Solar input during twilight hours? 200W doesn't sound like much when you factor in low winter angles and panel orientation. What's your average generation on a proper sunny day? I found my expectations were wildly optimistic until I actually logged real figures.
The worrying bit is whether this is normal battery self-discharge (which shouldn't be more than 1-2% monthly for decent LiFePO₄) or something systemic. I'm currently trying a Victron SmartShunt to get granular data on what's happening between dusk and dawn.
Worth knowing: Are you running 12V or 24V? What battery manufacturer? And crucially—are you actually measuring voltage drop or estimated capacity from the BMS display? The latter can be quite inaccurate.
Would be useful if others could share their actual overnight drain figures with comparable setups. Might help establish what's normal versus what needs investigating.