Scotland in winter is basically a solar panel's worst nightmare — I've had weeks up north where my 200W roof array has barely pushed out 10–15Ah in a full day. Genuinely grim.
A few things that made a real difference for me:
Shore power when you can get it — even a few hours on a campsite hookup every couple of days keeps you out of trouble. Not very off-grid purist, I know, but it's pragmatic.
Driving charges more than you'd think — I've got a decent B2B charger (Victron Orion-Tr Smart) wired in, and even a 45-minute run to a supermarket can put 15–20Ah back in. If you're moving around anyway, use it.
Audit your loads ruthlessly — a 100Ah lithium sounds like loads until you add up a compressor fridge (35–40Ah/day), lighting, phone charging, a diesel heater fan... it disappears fast.
Worth asking — what's your actual battery? Some of the cheaper cells genuinely don't perform as advertised, especially in the cold. My Fogstar Drift 100Ah has been solid, but I've heard horror stories about unbranded cells dropping usable capacity noticeably below 10°C.
The honest answer is that 100Ah is quite tight for full-time van life in overcast northern conditions without reliable solar. A second battery would probably give you more peace of mind than chasing better panels.
What loads are you running day-to-day? Might be easier to pinpoint where the drain's actually coming from.