Been mulling this over for a while and finally pulled the trigger last month. Picked up a used Nissan Leaf Gen 1 battery (24 kWh pack, probably down to around 18–19 kWh usable given the degradation) off eBay for £380. Paired it with a Victron MultiPlus-II 3000VA inverter/charger and a 600W solar array on the garage roof. So far it's handling our overnight loads no bother — fridge, a few lights, router, the usual.
The fiddly bit was the BMS situation. The Leaf pack has its own onboard BMS but it doesn't talk nicely to the Victron out of the box. I ended up using a Batrium BM6 watchmon to bridge the gap and set charge/discharge limits properly. Not a plug-and-play job by any means — took me a good three weekends of head-scratching and a fair bit of help from the Endless-Sphere forum to get it stable.
What I'm really curious about is whether anyone's gone down a similar route with other EV donor packs — BMW i3, Renault Zoe, Tesla Model S modules, that sort of thing. Particularly interested in how people are handling thermal management in a UK garage environment, because I've not done anything clever there yet and I'm a bit nervous about the colder months coming in.