The elephant in the room nobody's mentioned yet is the charging curve. Car alternators are designed to maintain a float voltage (~13.8V) once the engine's running, which is fine for starter batteries but absolutely terrible for properly charging leisure batteries. You'll get maybe 80% charge and then it plateaus—your batteries never fully cycle, sulphation sets in, capacity drops.
If you're serious about this, you need a smart regulator (Victron MPPT Lithium charger, or if you're budget-conscious, a Redarc SBI12 can work). But at that point you're looking at £300-500 before you've even fitted the alternator properly to your narrowboat engine.
Honestly? For a boat, I'd stick with a decent split-charge relay or VSR (voltage-sensitive relay) paired with a proper alternator upgrade if the original engine alternator is undersized. Simpler, fewer moving parts, fewer headaches when you're miles from shore.
What's your actual power draw like? Might be worth calculating whether a larger solar array would give you better returns. That's what most