Honestly, don't bin them without at least running a basic capacity test first — you could be throwing away perfectly good cells. Leaf packs are lithium manganese oxide chemistry (well, blended NMC/LMO depending on the generation), and they can hold up surprisingly well if the pack wasn't thermally abused.
What I'd do:
- Separate the modules — the Leaf uses paired cells in flat pouch modules, so you're working with those rather than individual cylindrical cells
- Check voltage on each module first — anything badly out of balance or sitting below ~3.5V per cell equivalent needs a closer look before you even bother capacity testing
- Run a proper charge/discharge cycle — I use an iCharger for this sort of thing, log the actual Ah you get back against the rated capacity
From my own narrowboat build I picked up some second-gen Leaf modules (the 40kWh pack generation) and after testing I'd say roughly 80% of modules from a used pack are still usable for stationary storage, even if they're not suitable for EV duty anymore.
The ones to bin are anything showing cell-level voltage divergence during discharge, physical swelling, or capacity below 70% of nameplate.
If you've got a decent BMS like a Daly or JK unit you can monitor cell-level behaviour once they're in a battery build too, which gives you early warning of any rogues.
What generation Leaf is the pack from? Makes a difference — the older 24kWh packs can be quite degraded by now but the 40kWh and 62kWh modules are often cracking value secondhand.