Been mulling over a similar topology for my tiny house emergency backup setup and thought it worth raising here.
My primary bank is a 200Ah Fogstar Drift LiFePO4, charged via a Victron SmartSolar MPPT 100/30. What I'm exploring is whether I can hang a pair of legacy lead-acid batteries off the back of that system using an Orion-Tr Smart (or the newer Orion XS) as a DC-DC charger — essentially treating the lithium bank as the "source" and the lead-acid banks as secondary loads that also happen to need proper charge profiling.
The Orion XS is engine-start-detection capable, but in a static off-grid context that feature is irrelevant — you'd just configure it for continuous mode. The more pressing question is whether the SmartSolar's absorption/float cycling on the lithium side will cause the Orion XS to behave oddly, given the lithium voltage curve is quite flat compared to what the Orion expects from a "source" battery.
In theory the Orion XS doesn't care what the source is, it just regulates output to whatever profile you've set for the lead-acid destination bank. So a lithium source sitting at 13.4V float should drive a perfectly respectable AGM charge cycle on the output side.
Has anyone actually run this configuration long-term? Specifically curious whether the SmartSolar's bulk-to-float transition causes the Orion XS to cut in and out repeatedly, or whether it just tracks smoothly. VictronConnect logging would presumably show this, but real-world experience would be more useful than my bench testing.