Running a small datacentre purely from inverter output is something I've been thinking about for a similar project — worth discussing the specifics here because there are a few UK-relevant wrinkles.
First, the frequency point: if you're in the UK, your UPS units, PDUs, and server PSUs all expect 50 Hz, so don't get drawn into a 60 Hz design from American forum threads. Most modern server PSUs are wide-input and will handle 50 Hz without complaint, but it's worth verifying.
On the Victron MultiPlus side — yes, they absolutely work in inverter-only mode with no AC input connected. I run a pair of MultiPlus-II 48/5000s in parallel here and they've never seen a grid connection. The key thing is configuring them correctly in VEConfigure so they're not sitting there waiting for an AC source that never arrives.
For ~200A at 230V (that's roughly 46 kW continuous — massive), you'd need a serious parallel stack. Victron's 48V MultiPlus-II units top out at 5kVA each, so you're looking at 10+ units just to hit that figure, plus the three-phase or split-phase considerations depending on your load distribution.
Battery sizing is the real conversation though. What's your actual continuous draw vs. peak? Datacentre loads tend to be reasonably predictable but the inrush on server boot cycles can be spiky.
What battery chemistry are you working with — LiFePO4? And have you considered 48V vs higher voltage bus (Victron's EasySolar or a custom 400V DC setup with different inverter topology)?
Curious what others here have done for compute-heavy off-grid