Had this exact thing on my boat setup last summer. The Pylontech was reading 100% SOC but the moment I kicked the inverter on and put any decent load through it, voltage would sag noticeably — sometimes 2-3V within the first few seconds.
Turned out to be a combination of things worth checking:
Internal resistance — as these cells age (or if they've been through some rough charge cycles), IR increases and you'll see more voltage sag under load even when nominally "full". Worth running a capacity test if you haven't.
Communication lag — the SOC display can lag behind reality, especially if the BMS hasn't had a proper full-cycle calibration recently. Mine was basically lying to me for weeks.
Top balancing — are all your cells balanced at the top? Uneven cells mean one or two hit the high voltage cutoff early, the BMS calls it full, but actual usable capacity is reduced.
What's your actual resting voltage reading before you apply load? On a US3000C you'd expect around 53.2V fully charged. If it's sitting lower than that and still claiming 100%, that's your first clue something's off.
Also — what are you running it with, a Victron system? The DVCC settings can sometimes cause odd behaviour with Pylontech if the charge parameters aren't quite dialled in.
Genuinely curious what others have experienced — I suspect this is more common than people realise, particularly in marine environments where temperature swings are a factor.