Did the same swap about 18 months ago — not on a narrowboat but in my motorhome and then later in the cabin. Same principles apply though, so worth chipping in.
Short answer: absolutely worth it. Long answer: it depends entirely on what you were putting up with before.
My old AGM setup on the motorhome was a constant battle. Monitoring state of charge was guesswork, I was always nursing it above 50% to avoid killing it early, and by year three it was a shadow of itself. Swapped to a pair of Fogstar Drift 100Ah cells wired in parallel and it was like a different vehicle. Full usable capacity, no babying required, and the weight saving was genuinely noticeable.
The one thing I'd flag for narrowboat use specifically — temperature. If your battery compartment gets properly cold in winter (and on a canal boat it will), make sure your BMS has low-temperature charge cutoff. Charging lithium below freezing is the one thing that'll genuinely damage the cells. Worth checking what protection your BMS actually offers rather than just assuming.
Also — what inverter/charger are you running? Some older units don't play nicely with lithium charge profiles. A Victron MultiPlus sorted that headache for me, though it's not a cheap fix.
Would be interested to hear how you're getting on with solar input as well — boat life seems like a brilliant use case for a decent MPPT setup given you're often sitting moored in open water with decent sky exposure.
What capacity did you go for in the end?