Had this exact saga on my static last summer — Victron BMV was sat there grinning at me showing 100% while my Fogstar cells were doing completely different things entirely.
Turned out my BMS wasn't actually balancing properly at top of charge, it was just claiming it was. Classic case of the BMV trusting the voltage tail-off and calling it done, when in reality a couple of cells were lagging behind like they'd had one too many.
Few things worth checking:
- Cell drift — chuck a proper cell-level monitor on there (I use a Heltec between the BMS and the battery terminals) and see what the spread actually looks like at alleged 100%
- BMS passive vs active balancing — passive balancers at low current are basically just warming the air, especially if your cells have drifted more than ~50mV apart
- Victron sync settings — your BMV might be syncing to 100% based on voltage alone rather than tail current, worth revisiting those parameters in VictronConnect
On my boat I ended up doing a manual top-balance on the cells individually before reconnecting — took an afternoon but sorted it right out.
What BMS are you running? Some of the cheaper units are basically just protection boards pretending to be smart. If it's a JK or similar you can usually pull the individual cell voltages via Bluetooth and catch it red-handed.
Anyone else had grief with BMV sync parameters causing this kind of phantom 100%? Feels like it comes up every few months on here.