Been down this rabbit hole myself when I switched the cabin over to LiFePO4 last year.
Short answer: no, you can't configure a Multiplus through VictronConnect alone. The app is great for monitoring and tweaking simpler kit like the MPPT controllers, but the Multiplus needs VE.Configure (Windows software) to change the bulk/absorption/float thresholds properly. Pain in the backside if you're not near a laptop.
What you actually need:
- MK3-USB interface (the dongle you're thinking of, ~£50ish)
- A Windows machine running VE.Configure 3
- Or alternatively, a Cerbo GX / GX Touch setup if you want remote config capability
I'm running a Multiplus-II 24/3000 and getting the charge profile dialled in for my Fogstar Drift cells took a bit of faffing. Key thing with LiFePO4 is killing the float or setting it very low — the Multiplus defaults are way too aggressive for lithium.
If you're on a boat (sounds like you might be from the "on board" comment), also worth checking your BMS has a proper charge disconnect signal wired to the Multiplus assistant — otherwise you're relying on the BMS to hard-cut under load which isn't ideal.
Anyone else found a decent workaround for configuring these without dragging a Windows laptop out? Tempted to just keep an old Lenovo beater dedicated to VE.Configure at the cabin but feels daft.