Had almost exactly this on my narrowboat last winter — drove me absolutely mad for about three weeks before I tracked it down.
Mine was switching to passthrough somewhere around 2–3am every night like clockwork. Turned out the battery voltage was dipping just enough to trigger the low battery cutoff threshold, even though the State of Charge on my Victron BMV-712 looked perfectly reasonable. The culprit was a dodgy cell in one of my old AGM batteries that was masking itself during the day but showing its true colours under overnight load.
A few things worth checking in your situation:
- VEConfigure settings — specifically your low battery cutoff and restart voltages. These can be surprisingly aggressive out of the box depending on battery type
- Are you on lithium or lead acid? If lithium, check whether your BMS is momentarily disconnecting and confusing the Multiplus
- What's your overnight load like? Even a small parasitic draw adds up over 8 hours
- Check the AC input voltage too — if shore power or a generator is fluctuating, sometimes the Multiplus will briefly drop to passthrough then recover
The VRM portal was genuinely brilliant for diagnosing mine — I could see the exact moment everything shifted and correlate it with battery voltage graphs.
What battery bank are you running and how old is it? That's usually where I'd start the investigation. Others on here will have seen more of these than me, would be curious whether anyone's had it caused by something completely different.