Curious what your actual power demands are, @FormerCop? That matters more than the voltage itself, honestly.
I'm running 48V in my static caravan setup with a Victron MultiPlus and it's been brilliant for the cable losses over longer runs, but that's overkill for a van with 3-4m of cabling like @BaySoul mentions. 24V is the sweet spot for most Sprinters IMO — good compromise between component availability (still cheaper than 48V kit), lower fire risk than 12V, and cable sizing stays sensible.
Main thing I'd push back on: don't just upgrade your battery capacity and call it done. What's actually drawing power? Fridge, heating, water pump, inverter? If you're planning proper 24V, you'll want a decent MPPT charge controller (Renogy or similar) and matching your loads to voltage becomes easier. A 200Ah 24V system will feel a lot less "pathetic" than throwing more 12V capacity at the problem.
What's your solar situation looking like? That often determines how much battery you actually need