Right, I'll share what I've learned from my setup here on the smallholding. Had AGM for years running the shepherds hut, but switched to LiFePO4 last year and honestly, it's been a game-changer.
The practical differences I've noticed:
AGM's been reliable — no fancy BMS needed, forgiving if you occasionally overcharge, and they work fine in cold weather. Cost less upfront too. But they hate deep cycles. I was getting maybe 3-4 years before capacity dropped noticeably.
LiFePO4 are a different beast. Yes, the initial outlay stung, but the usable capacity is genuinely higher. My 100Ah LiFePO4 feels more useful than my old 200Ah AGM setup ever did. Charge times are quicker, and I'm getting proper depth-of-discharge without worrying. A decent BMS is essential though — I went with a Victron Smart and haven't looked back.
Where it matters for me personally: The boat's now running LiFePO4, and for EV charging at the property, I needed the faster charge acceptance that lithium provides. Wouldn't have worked as smoothly with AGM.
The catch? Cold weather performance needs consideration, and you absolutely need a quality BMS. Cheap Chinese setups worry me.
If you're doing shallow cycling and want hassle-free, AGM works. But if you're seriously off-grid or want longevity, LiFePO4 repays itself. What's your actual use case? That'll make the answer clearer.